Программно получить order transitions workflows
/** @var \Drupal\state_machine\WorkflowManager $workflow_plugin_manager */
$workflow_plugin_manager = \Drupal::service('plugin.manager.workflow');
$orderTypes = \Drupal\commerce_order\Entity\OrderType::loadMultiple();
$workflowTransitions = []
/** @var $orderType \Drupal\commerce_order\Entity\OrderType */
foreach ($orderTypes as $orderType) {
$workflowTransitions[$orderType->id()] = $workflow_plugin_manager->createInstance($orderType->getWorkflowId())->getTransitions();
}